Physical And Chemical Properties

The structure of activated carbon is best described as a twisted network of defective carbon layer planes, cross-linked by aliphatic bridging groups (6). X-ray diffraction patterns of activated carbon reveal that it is nongraphitic, remaining amorphous because the randomly cross-linked network inhibits reordering of the structure even when heated to 3,000 °C (7). This property of activated carbon contributes to its most unique feature, namely, the highly developed and accessible internal pore structure. The surface area, dimensions, and distribution of the pores depend on the precursor and on the conditions of carbonization and activation. Pore sizes are classified (8) by the International Union of Pure and Applied Chemistry (IUPAC) as micropores (pore width <2 nm), mesopores (pore width 2-50 nm), and macropores (pore width >50 nm).

The surface area of activated carbon is usually determined by application of the Brunauer-Emmett-Teller (BET) model of physical adsorption (9,10) using nitrogen as the adsorptive (8). Typical commercial products have specific surface areas in the range 500-2,000 m2/g, but values as high as 3,500-5,000 m2/g have been reported for some activated carbons (11,12). In general, however, the effective surface area of a microporous activated carbon is far smaller because the adsorption of nitrogen in micropores does not occur according to the process assumed in the BET model, which results in unrealistically high values for surface area (10,13). Adsorption isotherms are usually determined for the appropriate adsorptives to assess the effective surface area of a product in a specific application. Adsorption capacity and rate of adsorption depend on the internal surface area and distribution of pore size and shape but are also influenced by the surface chemistry of the activated carbon (14). The macroporosity of the carbon is important for the transfer of adsorbate molecules to adsorption sites within the particle.

Functional groups are formed during activation by interaction of free radicals on the carbon surface with atoms such as oxygen and nitrogen, both from within the precursor and from the atmosphere (15). The functional groups render the surface of activated carbon chemically reactive and influence its adsorptive properties (6). Activated carbon is generally considered to exhibit a low affinity for water, which is an important property with respect to the adsorption of gases in the presence of moisture (16). However, the functional groups on the carbon surface can interact with water, rendering the carbon surface more hydrophilic (15). Surface oxidation, which is an inherent feature of activated carbon production, results in hydroxyl, carbonyl, and carboxylic groups that impart an amphoteric character to the carbon, so that it can be either acidic or basic. The electrokinetic properties of an activated carbon product are, therefore, important with respect to its use as a catalyst support (17). As well as influencing the adsorption of many molecules, surface oxide groups contribute to the reactivity of activated carbons toward certain solvents in solvent recovery applications (18).

In addition to surface area, pore size distribution, and surface chemistry, other important properties of commercial activated carbon products include pore volume, particle size distribution, apparent or bulk density, particle density, abrasion resistance, hardness, and ash content. The range of these and other properties is illustrated in Table 1 together with specific values for selected commercial grades of powdered, granular, and shaped activated carbon products used in liquid- or gas-phase applications (19).

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