Vaporliquid Separation

Product losses in evaporator vapor may result from foaming, splashing, or entrainment. Primary separation of liquid from vapor is accomplished in the vapor head by making the horizontal plan area large enough so that most of the entrained droplets can settle out against the rising flow of vapor. Allowable velocities are governed by the Souders-Brown equation: V = kV—- - p——„, in which k depends on the size distribution of droplets and the decontamination factor F desired. For most evaporators and for F between 100 and 10,000, k =

Rising Film Evaporator
FIG. 11-124 Boiling-point rise of aqueous solutions. °C = 5/9 (°F - 32).

0.245/(F — 50)0 4 (Standiford, Chemical Engineers' Handbook, 4th ed., McGraw-Hill, New York, 1963, p. 11-35). Higher values of k (to about 0.15) can be tolerated in the falling-film evaporator, where most of the entrainment separation occurs in the tubes, the vapor is scrubbed by liquor leaving the tubes, and the vapor must reverse direction to reach the outlet.

Foaming losses usually result from the presence in the evaporating liquid of colloids or of surface-tension depressants and finely divided solids. Antifoam agents are often effective. Other means of combating foam include the use of steam jets impinging on the foam surface, the removal of product at the surface layer, where the foaming agents seem to concentrate, and operation at a very low liquid level so that hot surfaces can break the foam. Impingement at high velocity against a baffle tends to break the foam mechanically, and this is the reason that the long-tube vertical, forced-circulation, and agitated-film evaporators are particularly effective with foaming liquids. Operating at lower temperatures and/or higher-dissolved solids concentrations may also reduce foaming tendencies.

Splashing losses are usually insignificant if a reasonable height has been provided between the liquid level and the top of the vapor head. The height required depends on the violence of boiling. Heights of 2.4 to 3.6 m (8 to 12 ft) or more are provided in short-tube vertical evaporators, in which the liquid and vapor leaving the tubes are projected upward. Less height is required in forced-circulation evaporators, in which the liquid is given a centrifugal motion or is projected downward as by a baffle. The same is true of long-tube vertical evaporators, in which the rising vapor-liquid mixture is projected against a baffle.

Entrainment losses by flashing are frequently encountered in an evaporator. If the feed is above the boiling point and is introduced above or only a short distance below the liquid level, entrainment losses may be excessive. This can occur in a short-tube-type evaporator if the feed is introduced at only one point below the lower tube sheet (Kerr, Louisiana Agric. Expt. Stn. Bull. 149, 1915). The same difficulty may be encountered in forced-circulation evaporators having too high a temperature rise through the heating element and thus too wide a flashing range as the circulating liquid enters the body. Poor vacuum control, especially during startup, can cause the generation of far more vapor than the evaporator was designed to handle, with a consequent increase in entrainment.

Entrainment separators are frequently used to reduce product losses. There are a number of specialized designs available, practically all of which rely on a change in direction of the vapor flow when the vapor is traveling at high velocity. Typical separators are shown in Fig. 11-122, although not necessarily with the type of evaporator with which they may be used. The most common separator is the cyclone, which may have either a top or a bottom outlet as shown in Fig. 11-122a and b or may even be wrapped around the heating element of the next effect as shown in Fig. 11-122/ The separation efficiency of a cyclone increases with an increase in inlet velocity, although at the cost of some pressure drop, which means a loss in available temperature difference. Pressure drop in a cyclone is from 10 to 16 velocity heads [Lawrence, Chem. Eng. Prog., 48, 241 (1952)], based on the velocity in the inlet pipe. Such cyclones can be sized in the same manner as a cyclone dust collector (using velocities of about 30 m/s (100 ft/s) at atmospheric pressure) although sizes may be increased somewhat in order to reduce losses in available temperature difference.

Knitted wire mesh serves as an effective entrainment separator when it cannot easily be fouled by solids in the liquor. The mesh is available in woven metal wire of most alloys and is installed as a blanket across the top of the evaporator (Fig. 11-122d) or in a monitor of reduced diameter atop the vapor head. These separators have low-pressure drops, usually on the order of 13 mm (a in) of water, and collection efficiency is above 99.8 percent in the range of vapor velocities from 2.5 to 6 m/s (8 to 20 ft/s) [Carpenter and Othmer, Am. Inst. Chem.

Eng. J., 1, 549 (1955)]. Chevron (hook-and-vane) type separators are also used because of their higher-allowable velocities or because of their reduced tendency to foul with solids suspended in the entrained liquid.

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