Equipment For Distillation And Gas Absorption Packed Columns

Packings are generally divided into three classes:

1. Random or dumped packings (Figs. 14-48 and 14-49) are discrete pieces of packing, of a specific geometric shape, that are "dumped" or randomly packed into the column shell.

2. Structured or systematically arranged packings (Fig. 14-50) are crimped layers of corrugated sheets (usually) or wire mesh. Sections of these packings are stacked in the column.

3. Grids. These are also systematically arranged packings, but instead of wire mesh or corrugated sheets, these use an open-lattice structure.

Random and structured packings are common in commercial practice. The application of grids is limited primarily to heat-transfer and wash services and/or where a high fouling resistance is required. Grids are discussed in detail elsewhere (Kister, Distillation Design, McGraw-Hill, New York, 1992).

Figure 14-51 is an illustrative cutaway of a packed tower, depicting typical internals. This tower has a structured-packed top bed and a random-packed bottom bed. Each bed rests on a support grid or plate. The lower bed has a holddown grid at its top to restrict packing uplift. Liquid to each of the beds is supplied by a liquid distributor. An intermediate distributor, termed a redistributor, is used to introduce feed and/or to remix liquid at regular height intervals. The intermediate distributor in Fig. 14-51 is not self-collecting, so a chevron collector is used to collect the liquid from the bed above. An internal pipe passes this liquid to the distributor below. The collected liquid is mixed with the fresh feed (not shown) before entering the distributor. The reboiler return enters behind a baffle above the bottom sump.

As illustrated, the packing needs to be interrupted and a distributor added at each point where a feed enters or a product leaves. A simple distillation tower with a single feed will have a minimum of two beds, a rectifying bed and a stripping bed.

Packing Objectives The objective of any packing is to maximize efficiency for a given capacity, at an economic cost. To achieve these goals, packings are shaped to

1. Maximize the .specific surface area, i.e., the .surface area per unit volume. This maximizes vapor-liquid contact area, and, therefore, efficiency. A corollary is that efficiency generally increases as the random packing size is decreased or as the space between structured packing layers is decreased.

2. Spread the surface area uniformly. This improves vapor-liquid contact, and, therefore, efficiency. For instance, a Raschig ring (Fig. 14-48a) and a Pall® ring (Fig. 14-48c) of an identical size have identical surface areas per unit volume, but the Pall® ring has a superior spread of surface area and therefore gives much better efficiency.

3. Maximize the void space per unit column volume. This minimizes resistance to gas upflow, thereby enhancing packing capacity.

A corollary is that capacity increases with random packing size or with the space between structured packing layers. Comparing with the first objective, a tradeoff exists; the ideal size of packing is a compromise between maximizing efficiency and maximizing capacity.

4. Minimize friction. This favors an open shape that has good aerodynamic characteristics.

5. Minimize cost. Packing costs, as well as the requirements for packing supports and column foundations, generally rise with the weight per unit volume of packing. A corollary is that packings become cheaper as the size increases (random packing) and as the space between layers increases (structured packing).

Random Packings Historically, there were three generations of evolution in random packings. The first generation (1907 to the 1950s) produced two basic simple shapes—the Raschig ring and the Berl saddle (Fig. 14-48a, b) that became the ancestors of modern random packings. These packings have been superseded by more modern packing and are seldom used in modern distillation practice.

The second generation (late 1950s to the early 1970s) produced two popular geometries—the Pall® ring, which evolved from the Raschig ring, andthe Intalox® saddle (Fig. 14-48c^f), which evolved from the Berl saddle.

BASF developed the Pall® ring by cutting windows in the Raschig ring and bending the window tongues inward. This opened up the ring, lowering the aerodynamic resistance and dramatically enhancing capacity. The bent tongues improved area distribution around the particle, giving also better efficiency. These improvements made the first generation Raschig rings obsolete for distillation.

FIG. 14-48 Common first- and second-generation random packings. (a) Raschig ring (metal, plastic, ceramic). (b) Berl saddle (ceramic). (c) Pall ring (metal). (d) Pall ring (plastic). (e) Intalox saddle (ceramic). (f) Super Intalox saddle (plastic). (Parts d, f, courtesy of Koch-Glitsch LP.)

FIG. 14-48 Common first- and second-generation random packings. (a) Raschig ring (metal, plastic, ceramic). (b) Berl saddle (ceramic). (c) Pall ring (metal). (d) Pall ring (plastic). (e) Intalox saddle (ceramic). (f) Super Intalox saddle (plastic). (Parts d, f, courtesy of Koch-Glitsch LP.)

Berl saddles (ceramics) are still used due to their good breakage resistance.

The second-generation packings are still popular and extensively used in modern distillation practice. The third generation (the mid-1970s until present) has produced a multitude of popular geometries, most of which evolved from the Pall® ring and Intalox® saddle. Some are shown in Fig. 14-49. A more comprehensive description of the various packings is given elsewhere (Kister, Distillation Design, McGraw-Hill, New York, 1992).

The third generation of packing was a significant, yet not large, improvement over the second generation, so second-generation packings are still commonly used.

Structured Packings Structured packings have been around since as early as the 1940s. First-generation structured packings, such as Panapak, never became popular, and are seldom used nowadays.

The second generation of structured packings began in the late 1950s with high-efficiency wire-mesh packings such as Goodloe®, Hyperfil®, and the Sulzer® (wire-mesh) packings. By the early 1970s, these packings had made substantial inroads into vacuum distillation, where their low pressure drop per theoretical stage is a major advantage. In these services, they are extensively used today. Their high cost, high sensitivity to solids, and low capacity hindered their application outside vacuum distillation.

The corrugated-sheet packing, first introduced by Sulzer in the late 1970s, started a third generation of structured packings. With a high capacity, lower cost, and lower sensitivity to solids, while still retaining a high efficiency, these corrugated-sheet packings became competitive with conventional internals, especially for revamps. The 1980s saw an accelerated rise in popularity of structured packings, to the point of their becoming one of the most popular column internals in use today.

Corrugated structured packings are fabricated from thin, corrugated (crimped) metal sheets, arranged parallel to one another. The corrugated sheets are assembled into an element (Figs. 14-50a, c and 14-51). The sheets in each element are arranged at a fixed angle to the vertical. Table 14-14 contains geometric data for several corrugated packings.

Geometry (Fig. 14-52) The crimp size defines the opening between adjacent corrugated layers. Smaller B, h, and S yield narrower openings, more sheets (and, therefore, greater surface area) per unit volume, and more efficient packing, but higher resistance to gas upflow, lower capacity, and enhanced sensitivity to plugging and fouling.

The corrugations spread gas and liquid flow through a single element in a series of parallel planes. To spread the gas and liquid uniformly in all radial planes, adjacent elements are rotated so that sheets of one element are at a fixed angle to the layer below (Fig. 14-51). For good spread, element height s is relatively short (typically 200 to 300 mm, 8 to 12 in) and the angle of rotation is around 90°.

The surfaces of a few structured packings (especially those used in highly fouling environments) are smooth. Most structured packings have a roughened or enhanced surface that assists the lateral spread of liquid, promotes film turbulence, and enhances the area available for mass transfer. Texturing commonly employed is embossing and grooving (Fig. 14-50a, b).

The surfaces of most (but not all) structured packings contain holes that serve as communication channels between the upper and lower surfaces of each sheet. If the holes are too small, or nonexistent, both sides of a sheet will be wet only at low liquid rates. At high liquid rates, sheeting or blanking will cause liquid to run down the top surface with little liquid wetting the bottom surface [Chen and Chuang, Hydroc. Proc. 68(2), 37 (1989)], which may lower efficiency. Usually, but not always, the holes are circular (Fig. 14-50a, b), about 4 mm in diameter. Olujic et al. (Distillation 2003: Topical Conference Proceedings, p. 523, AlChE, 2003, Spring National Meeting, New Orleans, La.) showed that the hole diameter has a complex effect, strongly dependent on packing size, on both capacity and efficiency.

Inclination Angle In each element, corrugated sheets are most commonly inclined at about 45° to the vertical (typically indicated by the letter 'Y' following the packing size). This angle is large enough for good drainage of liquid, avoiding stagnant pockets and regions of liquid accumulation, and small enough to prevent gas from bypassing the metal surfaces. In some packings, the inclination angle to the vertical is steepened to 30° (typically indicated by the letter X following the

Downcomer Distillation

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